To access the Concept2 PM3/4/5 over a usb connection you also need to install the PyUSB library onto your Raspberry Pi. See below for the most recent version tested:
Python.org - pypi.python.org/pypi/pyusb/1.0.2*
Old PyUSB archive:
Walac PyUSB - https://github.com/walac/pyusb
*Thanks to Mark Pettit for this notification